A comprehensive experimental, multivariate statistical, and DFT computational analysis of the catalytic oxidation of benzyl alcohols mediated by Mn( iii ) and Fe( iii ) metalloporphyrins

Dalton Transactions 2026

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Authors: Larissa Chimilouski, Sheetal Ranaut, William Henrique Slominski, Patrícia Salvador Tessaro, Gilson de Freitas Silva, Edmar Martendal, Cláudio N. Verani, Shivnath Mazumder, Fernando R. Xavier
DOI: 10.1039/d5dt02798e
Cited by: 2
References: 49

Abstract

The catalytic oxidation of benzyl alcohols was optimized based on multivariate analysis, and advanced DFT calculations support distinct mechanistic pathways for each metalloporphyrin.

Fields of Study & Subjects

Porphyrin and Phthalocyanine Chemistry Metal-Catalyzed Oxygenation Mechanisms Inorganic and Organometallic Chemistry

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
13
Pages
5117–5129
Publication date
1 January 2026
Language
EN