Electrophilic lithium carbazolide as an efficient trap for organolithium species: complexes containing monomeric n -BuLi, t -BuLi and Me 3 SiCH 2 Li units

Dalton Transactions 2026

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Authors: Mikhail A. Bogachev, Alexander N. Selikhov, Anton V. Cherkasov, Rinat R. Aysin, Alexander A. Trifonov
DOI: 10.1039/d5dt02800k
Cited by: 0
References: 100

Abstract

The metalation of 3,6-di- tert -butyl-1,8-bis-(2,4,6-triisopropylphenyl)-9 H -carbazole ( 1 ) with n -BuLi, t -BuLi or Me 3 SiCH 2 Li (1 : 2) in heptane affords binuclear ionic complexes containing monomeric n -BuLi, t -BuLi and Me 3 SiCH 2 Li units.

Fields of Study & Subjects

Coordination Chemistry and Organometallics Synthesis and characterization of novel inorganic/organometallic compounds Organometallic Complex Synthesis and Catalysis

Publication details

Journal / source
Dalton Transactions
Volume
55
Issue
6
Pages
2452–2464
Publication date
1 January 2026
Language
EN