Cationic heteroleptic Ni( ii ) complexes of dithiocarbamate and phosphine ligands: synthesis, characterization and proton reduction study

Dalton Transactions 2026

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Authors: Sarvesh Kumar Pal, Anjali Mishra, Gaurav K. Mishra, Ruben Hansson, Vishal Jaiswal, Ebbe Nordlander, George C. Lisensky, Amrendra Kumar Singh, Nanhai Singh, Prem Lama, Kamlesh Kumar
DOI: 10.1039/d5dt02840j
Cited by: 2
References: 70

Abstract

), and faradaic efficiency (88%) is attributed to the conformational flexibility of the six-membered chelate ring in 3 due to the dppp ligand. Both experimental data and DFT calculations support an ECEC mechanism for the HER catalysed by heteroleptic Ni(II) complexes with the formation of Ni(III)-H intermediate species.

Fields of Study & Subjects

Organometallic Compounds Synthesis and Characterization Inorganic and Organometallic Chemistry Organometallic Complex Synthesis and Catalysis

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
8
Pages
3375–3387
Publication date
1 January 2026
Language
EN