Zero valent iron and nickel coordination chemistry: metal atoms as direct approach to bis(benzene)chromium bridged N-heterocyclic silylene complexes

Dalton Transactions 2026

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Authors: Johannes M. Emmert, Jörg Rust, Christian W. Lehmann, Jörg J. Schneider
DOI: 10.1039/d5dt02957k
Cited by: 2
References: 45

Abstract

A bis(benzene) chromium bridged bidentate organometallic silylene pincer ligand is introduced for zerovalent iron and nickel. The pincer ligand and its Fe complex are accessible by a direct metal-atom route under extremely mild chimie douce conditions.

Fields of Study & Subjects

Organometallic Complex Synthesis and Catalysis Catalytic Cross-Coupling Reactions Synthesis and characterization of novel inorganic/organometallic compounds

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
11
Pages
4657–4663
Publication date
1 January 2026
Language
EN