Cubane lanthanoid complexes with tridentate [O, PO, O] coordination using tris(5- tert -butyl-2-hydroxyphenyl)-phosphine oxide ligands: synthesis, characterisation, and magnetic behaviour
Abstract
-aryl phosphine oxide ligand to balance the reactivity and solubility of reactants to generate these unique compounds. DC magnetic studies for 1 and 2 reveal that complexes support weak antiferromagnetic coupling between the centres, with 2 exhibiting a frequency dependence in the zero field out-of-phase component of the AC susceptibility.
Fields of Study & Subjects
Magnetism in coordination complexes
Lanthanide and Transition Metal Complexes
Inorganic and Organometallic Chemistry
Publication details
- Journal / source
- Dalton Transactions
- Volume
- 55
- Issue
- 13
- Pages
- 5408–5415
- Publication date
- 1 January 2026
- Language
- EN