Proton-conducting coordination polymers formed from bipyridine phosphonate ligands

Dalton Transactions 2026 Open access

Read full text
Authors: Prajakta Mohan Ramteke, Tomáš Plecháček, Matouš Kloda, Ján Rohlíček, Anna Vykydalová, Klára Melánová, Dmytro Bavol, Karel Škoch, Marco Taddei, Jan Demel, Jan Hynek
DOI: 10.1039/d5dt02997j
Cited by: 2
References: 59

Abstract

, which is achieved by ICR-26 at 92% humidity and a temperature of 306 K. Activation energies indicate the vehicle mechanism of proton transport in ICR-25 and the proton-hopping (Grotthuss) mechanism in the case of ICR-26. We thereby propose that using the N-heteroaromatic phosphonate ligands is an efficient method for the construction of proton-conducting coordination polymers.

Fields of Study & Subjects

Metal-Organic Frameworks: Synthesis and Applications Chemical Synthesis and Characterization Fuel Cells and Related Materials

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
14
Pages
5622–5634
Publication date
1 January 2026
Language
EN