Band alignment and interfacial electrostatics: unraveling the dynamic space charge layer in all-solid-state batteries

EES batteries. 2026 Open access

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Authors: Hao Lai, Jinli Liu, Qiqiang Huang, Chenxi Li, Peng Zhang, Xiaofeng Luo, Lewei Shi, Zhibo Han, Wei Peng, Xingtai Liu, Xinman Chen, Languang Lu
+4 more Xuning Feng, Dongsheng Ren, Minggao Ouyang, Xiang Liu
DOI: 10.1039/d5eb00244c
Cited by: 6
References: 149

Abstract

This review summarizes SOC-dependent, multiscale effects of the space charge layer (SCL) in all-solid-state batteries and how it regulates Li + redistribution, built-in fields, and activation energy, governing ion transport and interfacial impedance.

Fields of Study & Subjects

Advancements in Battery Materials Advanced Battery Materials and Technologies Advanced battery technologies research

Publication details

Journal / source
EES batteries.
Publisher
Royal Society of Chemistry (RSC)
Volume
2
Issue
2
Pages
313–336
Publication date
1 January 2026
Language
EN