Unraveling bulk degradation mechanisms of wide-bandgap perovskite absorbers for tandem applications

Read full text
Authors: Chiara Ongaro, Mostafa Othman, Christophe Ballif, Christian M. Wolff, Aïcha Hessler‐Wyser
Cited by: 4
References: 137

Abstract

are predominantly limited by their strong propensity for converting to non-perovskite phases. In both material families, the crystallization pathway critically dictates the spatial distribution of components and the incorporation of defects. The resulting heterogeneities, together with nanoscale impurities and secondary phases, serve as initiation sites for absorber degradation under operational conditions. This review discusses emerging strategies aimed at overcoming these challenges, including compositional engineering, crystallization control, and targeted passivation. By addressing the root causes of bulk instability, this work outlines guidance toward achieving the long-term stability required for WBG perovskites in tandem photovoltaic technologies.

Fields of Study & Subjects

Perovskite Materials and Applications solar cell performance optimization Chemical and Physical Properties of Materials

Publication details

Journal / source
EES solar.
Publisher
Royal Society of Chemistry (RSC)
Volume
2
Issue
2
Pages
293–314
Publication date
1 January 2026
Language
EN