Engineering a Mn polarization center in Bi 19 S 27 Cl 3 for efficient ammonia production under near-infrared light

Green Chemistry 2026

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Authors: Jiajing Zhang, Rong Tang, Jun Xiong, Xuhao Yang, Xiaojiao Du, Wei Jiang, Jun Di
DOI: 10.1039/d5gc06958k
Cited by: 1
References: 62

Abstract

Leveraging the Jahn–Teller effect, Mn-doping creates polarized active sites in Bi 19 S 27 Cl 3 . This electronic restructuring enables efficient NIR-light-driven photocatalytic reduction of NO 3 − to NH 3 , achieving a rate of 132 µmol g −1 h −1 .

Fields of Study & Subjects

Ammonia Synthesis and Nitrogen Reduction Advanced Photocatalysis Techniques TiO2 Photocatalysis and Solar Cells

Publication details

Journal / source
Green Chemistry
Publisher
Royal Society of Chemistry (RSC)
Volume
28
Issue
10
Pages
4680–4688
Publication date
1 January 2026
Language
EN