DBU-catalyzed metal-free C–O bond cleavage of lignin model compounds under mild conditions
Abstract
In a mild, metal-free protocol, lignin β-O-4 models are oxidized to ketones and then undergo DBU-promoted oxidative C–O bond cleavage in DMSO/H 2 O under O 2 (120 °C), producing acetophenones and phenols.
Fields of Study & Subjects
Lignin and Wood Chemistry
Oxidative Organic Chemistry Reactions
Plant-derived Lignans Synthesis and Bioactivity
Publication details
- Journal / source
- New Journal of Chemistry
- Volume
- 50
- Issue
- 10
- Pages
- 4259–4263
- Publication date
- 1 January 2026
- Language
- EN