Transmetalated synthesis of homodinuclear Mn II and Co II complexes containing Robson type macrocyclic ligands: crystal structure, magnetic investigation and DFT calculations

New Journal of Chemistry 2026

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Authors: Abhishek Pramanik, Samit Majumder, Susanta Hazra, Sasankasekhar Mohanta
DOI: 10.1039/d5nj04703j
Cited by: 1
References: 145

Abstract

Transmetallation in the open atmosphere of Fe III by Mn II and Pb II by Co II produces, respectively, MnII2 and CoII2 complexes instead of usual Mn III and Co III containing systems. Weak magnetic interactions have been well rationalized by DFT calculations.

Fields of Study & Subjects

Magnetism in coordination complexes Metal-Catalyzed Oxygenation Mechanisms Metal complexes synthesis and properties

Publication details

Journal / source
New Journal of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Volume
50
Issue
20
Pages
8802–8813
Publication date
1 January 2026
Language
EN