Pd II and Pt II complexes bearing acetamide and thioacetamide functionalized heteroscorpionates and their application in the hydrosilylation of terminal alkynes

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Authors: Mariana C. Ortiz-Hernández, V. I. Noguez-Maldonado, V. Salazar-Pereda, Simplicio González Montiel, Daniel Mendoza‐Espinosa, Andrés Suárez, C. Cristobal
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References: 62

Abstract

Reaction of ligand N -phenyl-2,2-bis(3,5-dimethylpyrazol-1-yl)thioacetamide (pbptamH) with MCl 2 (M = Pd, Pt) in acetonitrile results in the formation of cationic complexes 1a-b with the general formula [(pbptamH) 2 M]Cl 2 .

Fields of Study & Subjects

Organometallic Complex Synthesis and Catalysis Organoboron and organosilicon chemistry Inorganic and Organometallic Chemistry

Publication details

Journal / source
New Journal of Chemistry
Volume
50
Issue
10
Pages
4415–4424
Publication date
1 January 2026
Language
EN