A nanoscale view on oligo(ethylene glycol) self-assembled monolayer hydration
Abstract
, and nano IR spectroscopy revealed direct spectroscopic evidence for different conformations prevalent in these domains. Hydration experiments conducted in an environment with increased humidity resulted in the nano-domains being hydrated to different extents. Water uptake led to an irreversible conformational transition of the helical domains. Additionally, nano IR spectroscopy demonstrated the absorbance of two differently hydrogen-bound water populations. These results shed new light on the nanophase behaviour of OEG SAMs and help to explain how nano-structure influences their protein repellency.
Fields of Study & Subjects
Polymer Surface Interaction Studies
Supramolecular Self-Assembly in Materials
Surface Chemistry and Catalysis
Publication details
- Journal / source
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 18
- Issue
- 11
- Pages
- 5884–5895
- Publication date
- 1 January 2026
- Language
- EN