CO 2 /epoxides ring-opening copolymerization towards hydroxy-functionalized polycarbonates
Abstract
Ring-opening copolymerization of CO 2 with BnGE and/or CHO promoted by an Al/Fe/Co complex or BEt 3 , combined with PPNCl, afforded PBnGEC and P(BnGEC- co -CHC). TBD-depolymerization of PBnGEC, PCHC and P(BnGEC- co -CHC) returned both corresponding cyclic carbonates.
Fields of Study & Subjects
Carbon dioxide utilization in catalysis
biodegradable polymer synthesis and properties
Polymer Foaming and Composites
Publication details
- Journal / source
- Polymer Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 17
- Issue
- 10
- Pages
- 1005–1018
- Publication date
- 1 January 2026
- Language
- EN