Systematic control of the spin crossover profile in dinuclear iron( iii ) complexes via the bridging ligand redox-state

Inorganic Chemistry Frontiers 2026

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Authors: Jett T. Janetzki, Maxim G. Chegerev, I. Haseena Ismail, Robert W. Gable, Roger J. Mulder, Guy N. L. Jameson, Lorenzo Sorace, Alyona A. Starikova, Colette Boskovic
DOI: 10.1039/d5qi02155c
Cited by: 2
References: 139

Abstract

The spin crossover behavior in dinuclear Fe III complexes is tuned by changing the oxidation state of the bridging bis(dioxolene) ligand, with the mixed-valence form imparting an asymmetric ligand field that drives a two-step interconversion.

Fields of Study & Subjects

Magnetism in coordination complexes Metal-Catalyzed Oxygenation Mechanisms Lanthanide and Transition Metal Complexes

Publication details

Journal / source
Inorganic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
10
Pages
4375–4395
Publication date
1 January 2026
Language
EN