Confined metal centres in a symmetric cage: mono- and heterodinuclear complexes for photocatalytic hydrogen evolution

Inorganic Chemistry Frontiers 2026 Open access

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Authors: Melvin Raulin, Federico Droghetti, Davide Zeppilli, Federico Begato, Pradip Kumar Mondal, Marzio Rancan, Giulia Licini, Laura Orian, Mirco Natali, Cristiano Zonta
DOI: 10.1039/d5qi02424b
Cited by: 1
References: 56

Abstract

Selective mono-, homo- and heterodinuclear metalation is achieved within a chiral TPMA cage, offering a unified platform to disentangle confinement, nuclearity and second-sphere proton-relay effects in photocatalytic hydrogen evolution.

Fields of Study & Subjects

Supramolecular Chemistry and Complexes Magnetism in coordination complexes Metalloenzymes and iron-sulfur proteins

Publication details

Journal / source
Inorganic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
6
Pages
2470–2477
Publication date
1 January 2026
Language
EN