Core–shell [Cu 45 (C 6 H 11 S) 24 (P(PhF) 3 ) 4 H 19 ] 2+ nanocluster: synthesis, structure and catalytic hydroboration
Abstract
The core–shell copper hydride nanocluster, [Cu 45 (C 6 H 11 S) 24 (P(PhF) 3 ) 4 H 19 ] 2+ , featuring a distinct structure, exhibits excellent catalytic activity for the hydroboration of terminal alkynes, achieving yields of up to 98.3%.
Fields of Study & Subjects
Nanocluster Synthesis and Applications
Supramolecular Chemistry and Complexes
Catalytic Cross-Coupling Reactions
Publication details
- Journal / source
- Inorganic Chemistry Frontiers
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 13
- Issue
- 7
- Pages
- 3026–3036
- Publication date
- 1 January 2026
- Language
- EN