Harnessing alkaline-earth metal reactivity: mechanistic insights into alkene and alkyne functionalization via organomagnesium( ii ) and organobarium( ii ) catalysis
Abstract
A comprehensive in silico exploration establishes fundamental understanding for alkaline-earth catalysis, proving these earth-abundant metals can function as transition-metal mimics with complementary reactivities in migratory insertion reactions.
Fields of Study & Subjects
Catalytic Cross-Coupling Reactions
Coordination Chemistry and Organometallics
Organometallic Complex Synthesis and Catalysis
Publication details
- Journal / source
- Organic Chemistry Frontiers
- Volume
- 13
- Issue
- 5
- Pages
- 1602–1616
- Publication date
- 1 January 2026
- Language
- EN