Pd( ii )-catalyzed intramolecular diarylation of alkynes via dual C–H activation: modular access to azafulvalene-based bis(polycyclic) aromatic enes

Organic Chemistry Frontiers 2026 Open access

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Authors: Tienan Jin, Sho AIDA, Takuma Sato, Masahiro Terada
DOI: 10.1039/d5qo01688f
Cited by: 1
References: 40

Abstract

Structurally diverse azafulvalene-based bis(polycyclic) aromatic enes with precisely positioned nitrogen atoms were synthesized from N -aryl and 2-aryl biarylalkynyl indoles via Pd-catalyzed dual aromatic C–H activation.

Fields of Study & Subjects

Catalytic C–H Functionalization Methods Catalytic Cross-Coupling Reactions Synthesis and Reactivity of Heterocycles

Publication details

Journal / source
Organic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
7
Pages
2143–2151
Publication date
1 January 2026
Language
EN