An air-stable chiral P,N-ligand/PdCl 2 partner enables a highly enantioselective oxidative homocoupling of naphthylboronic acids/boronates only in an oxygen atmosphere

Organic Chemistry Frontiers 2026

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Authors: Guo Cheng, Jing-Liang Yu, Qian-Mao Zhang, Zhen-Yu Yang, Fang Tian, Li‐Xin Wang
DOI: 10.1039/d5qo01752a
Cited by: 1
References: 59

Abstract

A highly enantioselective oxidative homocoupling of naphthylboronic acids/boronates was achieved for the first time in the presence of an easily available chiral P,N-ligand/PdCl 2 complex only in an oxygen atmosphere at high temperature conditions.

Fields of Study & Subjects

Catalytic C–H Functionalization Methods Asymmetric Hydrogenation and Catalysis Organoboron and organosilicon chemistry

Publication details

Journal / source
Organic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
8
Pages
2410–2416
Publication date
1 January 2026
Language
EN