Cerium-doped UiO-66-supported Pd catalysts: activity enhancement and deactivation pathways in the carbonylation of methyl nitrite to DMC
Abstract
-UiO-66, with the highest thermal stability (547.26 °C), presented the highest catalytic stability in DMC synthesis. It was proven that the damage of C[double bond, length as m-dash]O and the migration of Pd atoms occurred due to the replacement of ligands and metal clusters, which led to catalytic deactivation.
Fields of Study & Subjects
Carbon dioxide utilization in catalysis
Catalytic Cross-Coupling Reactions
Chemical Synthesis and Reactions
Publication details
- Journal / source
- RSC Advances
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 16
- Issue
- 2
- Pages
- 1202–1211
- Publication date
- 1 January 2026
- Language
- EN