Understanding the influence of group 13 elements on the reactivity of G13–As–Ge imine analogues in 1,3-addition with methyl iodide
Abstract
The pronounced relativistic effects associated with heavier group 13 element induce angular contraction in G13–As–Ge frameworks, thereby facilitating superior orbital interaction with CH 3 I and accelerating the reaction by reducing the energy barrier.
Fields of Study & Subjects
Synthesis and characterization of novel inorganic/organometallic compounds
Organoboron and organosilicon chemistry
Chemical Reaction Mechanisms
Publication details
- Journal / source
- RSC Advances
- Volume
- 16
- Issue
- 4
- Pages
- 3735–3752
- Publication date
- 1 January 2026
- Language
- EN