Solution structures in alkali nitrates and nitrites at high concentrations

RSC Advances 2026 Open access

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Authors: Sebastian T. Mergelsberg, Trent R. Graham, Emily T. Nienhuis, Hsiu-Wen Wang, Ashley R. Kennedy, Lawrence M. Anovitz, Jacob G. Reynolds, Robert G. Felsted, Charles T. Resch, Carolyn I. Pearce
DOI: 10.1039/d5ra07630g
Cited by: 2
References: 52

Abstract

undergoes a concentration-induced transition to a uniquely ordered state, resulting in a highly structured solution. This work provides a direct, mechanistic explanation for how cation choice dictates the 'rules' of solution architecture, offering a predictive basis for understanding phase behavior in complex industrial and environmental systems.

Fields of Study & Subjects

Spectroscopy and Quantum Chemical Studies Ammonia Synthesis and Nitrogen Reduction Electrostatics and Colloid Interactions

Publication details

Journal / source
RSC Advances
Publisher
Royal Society of Chemistry (RSC)
Volume
16
Issue
15
Pages
13347–13357
Publication date
1 January 2026
Language
EN