From structure to function: a one-dimensional palladium( ii ) hybrid for real-sample hydroquinone detection

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Authors: Sarra Bougossa, Naoufel Ben Hamadi, Jassem Wannassi, Noureddine Mhadhbi, Jeanneau Erwann, Ahlem Guesmi, Lotfi KHEZAMI, Houcine Barhoumi, Houcine Naı̈li
Cited by: 1
References: 83

Abstract

edge-sharing octahedra, stabilized by extensive hydrogen bonding and π⋯π stacking interactions involving the organic cations. Infrared spectroscopy confirmed the presence of key functional groups and intermolecular interactions. UV-vis diffuse reflectance spectroscopy indicated significant absorption in the UV range, with an optical band gap of 2.18 eV, indicating semiconducting behavior. The material's structural characteristics and optical behavior suggest its suitability for applications in photocatalysis, sensing, and proton conduction. An electrochemical sensor exhibiting high sensitivity and selectivity for hydroquinone (HQ) detection was developed and tested using differential pulse voltammetry. This sensor demonstrated a low detection limit of 0.02 µM and exhibited a broad linear response range spanning 0.02 to 10 µM. It maintained outstanding performance even when common interfering substances were present. Application to real samples provided recovery rates between 95.4% and 102.4%, underscoring its potential for use in environmental surveillance and quality control purposes.

Fields of Study & Subjects

Electrochemical sensors and biosensors Metal-Organic Frameworks: Synthesis and Applications Advanced biosensing and bioanalysis techniques

Publication details

Journal / source
RSC Advances
Publisher
Royal Society of Chemistry (RSC)
Volume
16
Issue
11
Pages
9530–9546
Publication date
1 January 2026
Language
EN