Redox-mediator enhanced electrochemiluminescence under non-aqueous conditions

Chemical Science 2026 Open access

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Authors: Steven J. Blom, Fazeleh Mesgari, El M. S. Martin, Egan H. Doeven, David J. Hayne, Timothy U. Connell, Peter J. Barnard, Narges Saeedizadeh, Seyed Mohammad Jafar Jalali, Paul S. Francis
DOI: 10.1039/d5sc08710d
Cited by: 3
References: 54

Abstract

(acac) because the required excitation pathways were either thermodynamically inaccessible or initiated at the same potentials as competing reactions involving the direct electrochemical oxidation of the luminophore. These findings establish that neutral iridium(iii) complexes can function as redox mediators in non-aqueous co-reactant ECL systems and provide mechanistic insight for extending redox-mediator-enhanced ECL to new luminophores and applications.

Fields of Study & Subjects

Advanced biosensing and bioanalysis techniques bioluminescence and chemiluminescence research Electrochemical Analysis and Applications

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
19
Pages
9481–9491
Publication date
1 January 2026
Language
EN