Interplay between ligand field strength and the nephelauxetic effect in chromium( iii ) complexes with anionic amido ligands

Chemical Science 2026 Open access

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Authors: Polina Yaltseva, Benjamin Wittwer, Daniel Leitner, F. R. Neururer, Frank Tambornino, Alexander Schmidt, Dominik Munz, Oliver S. Wenger, Stephan Hohloch
DOI: 10.1039/d5sc09069e
Cited by: 3
References: 112

Abstract

Carbazolide-based pincer ligands bearing NHCs/MICs enhance ligand field strength in Cr III complexes with minimal impact on the Racah parameter B , maintaining NIR-active spin-flip excited states and extending their lifetimes, establishing design principles in first-row transition metal photophysics.

Fields of Study & Subjects

Magnetism in coordination complexes Metal complexes synthesis and properties Lanthanide and Transition Metal Complexes

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
17
Pages
8760–8771
Publication date
1 January 2026
Language
EN