From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulation
Abstract
) mainly comes from the parallel-arranged organic groups, with their contribution accounting for 89.49%. This work proves that the arrangement of π-conjugated organic ligands can be modulated to a parallel mode by adjusting the number of hydrogen bond donors. Combined with a wide HOMO-LUMO gap, the functional group modulation method is an effective strategy for designing and synthesizing ultraviolet NLO materials.
Fields of Study & Subjects
Crystal Structures and Properties
Nonlinear Optical Materials Research
Inorganic Fluorides and Related Compounds
Publication details
- Journal / source
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 17
- Issue
- 13
- Pages
- 6586–6592
- Publication date
- 1 January 2026
- Language
- EN