Cooperative metathesis of H–H/Sn–C Ar bonds in stannylene-Ni 0 systems

Chemical Science 2026 Open access

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Authors: Jonas Gilch, Philip M. Keil, Mustapha Iddrisu, Tibor Szilvasi, Terrance J. Hadlington
DOI: 10.1039/d5sc09496h
Cited by: 3
References: 61

Abstract

Sn( ii ) and Ni(0) in a stannylene → Ni complex cooperatively activate H 2 , leading to Sn–C/H–H bond metathesis. The formed H-bridged nickela-stannylene is indicative of net reduction at Sn, via a formal oxidative addition/reductive elimination process.

Fields of Study & Subjects

Synthetic Organic Chemistry Methods Organometallic Complex Synthesis and Catalysis N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
16
Pages
7938–7946
Publication date
1 January 2026
Language
EN