Carbon–iodine atropisomerism on triazole and triazolium frameworks: a breathing axle with divergent adaptivity
Abstract
halogen bonding and electrostatic interaction. Together, these results establish the hypervalent C-I(iii) bond as a stereoelectronically tunable rotational element-an axle that enables molecular rotors combining well-defined rotational dynamics with switchable recognition behavior.
Fields of Study & Subjects
Axial and Atropisomeric Chirality Synthesis
Supramolecular Chemistry and Complexes
Synthesis and Properties of Aromatic Compounds
Publication details
- Journal / source
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 17
- Issue
- 12
- Pages
- 6109–6115
- Publication date
- 1 January 2026
- Language
- EN