Lithium coordination disorder controlling ionic conductivity in mixed-halide borate glasses

Journal of Materials Chemistry A 2026 Open access

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Authors: Yohei Onodera, Yasuyuki Takimoto, Hiroyuki Hijiya, Noriyoshi Kayaba, Masamichi Tanida, Kazutaka Ikeda, Shinji Kohara
DOI: 10.1039/d5ta10123a
Cited by: 1
References: 73

Abstract

Lithium-specific pair distribution function analysis shows that the coexistence of multiple LiO₃X₂ (X = Cl, Br) polyhedral units in mixed-halide borate glasses disrupts lithium migration pathways, leading to reduced ionic conductivity.

Fields of Study & Subjects

Glass properties and applications Advanced Battery Materials and Technologies Thermal Expansion and Ionic Conductivity

Publication details

Journal / source
Journal of Materials Chemistry A
Publisher
Royal Society of Chemistry (RSC)
Volume
14
Issue
35
Pages
23026–23037
Publication date
1 January 2026
Language
EN