Stibine-catalyzed selective conversion of nitroarenes to hydroxylanilines through deoxygenation and hydroboration processes
Abstract
We accomplish the synthesis of hydroxylanilines from nitroarenes by employing HBpin as the reductant and a simple stibine ( n Bu 3 Sb) as the catalyst, demonstrating the unique chemoselectivity of antimony redox catalysis.
Fields of Study & Subjects
Asymmetric Hydrogenation and Catalysis
Nanomaterials for catalytic reactions
Organoboron and organosilicon chemistry
Publication details
- Journal / source
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 62
- Issue
- 27
- Pages
- 7150–7154
- Publication date
- 1 January 2026
- Language
- EN