Photoredox-catalysed cyclisation of carbyne equivalents with alkenes and aldehydes to dihydrofurans

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Authors: Jiyuan Gao, Wencheng Han, Wen-Deng Liu, Ziyu Jiang, Xue song, Jiannan Zhao
Cited by: 1
References: 59

Abstract

Herein, we report a multicomponent cyclisation reaction that employs a diazomethyl-substituted hypervalent iodine reagent as a carbyne source in combination with simple alkenes and aldehydes. This strategy successfully constructs dihydrofuran scaffolds, featuring broad substrate scope and excellent functional group compatibility. This work underscores the utility of carbyne as a versatile intermediate in organic synthesis.

Fields of Study & Subjects

Cyclopropane Reaction Mechanisms Oxidative Organic Chemistry Reactions Catalytic C–H Functionalization Methods

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
23
Pages
6332–6336
Publication date
1 January 2026
Language
EN