Photoredox-catalysed cyclisation of carbyne equivalents with alkenes and aldehydes to dihydrofurans
Abstract
Herein, we report a multicomponent cyclisation reaction that employs a diazomethyl-substituted hypervalent iodine reagent as a carbyne source in combination with simple alkenes and aldehydes. This strategy successfully constructs dihydrofuran scaffolds, featuring broad substrate scope and excellent functional group compatibility. This work underscores the utility of carbyne as a versatile intermediate in organic synthesis.
Fields of Study & Subjects
Cyclopropane Reaction Mechanisms
Oxidative Organic Chemistry Reactions
Catalytic C–H Functionalization Methods
Publication details
- Journal / source
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 62
- Issue
- 23
- Pages
- 6332–6336
- Publication date
- 1 January 2026
- Language
- EN