Strain-ring construction enabled by boronate complex/1,2-metalate rearrangement
Abstract
skeletal reorganization even under conditions with increased strain. This review compiles key developments in strain-ring construction triggered by boronate complex/1,2-metalate rearrangement, spanning mono-boronic esters to multi-boron frameworks. The collected studies illustrate how electrophilic, radical, and metal-mediated activation modes can be strategically combined with boron migration to access strained carbocycles and heterocycles with high stereocontrol.
Fields of Study & Subjects
Organoboron and organosilicon chemistry
Catalytic Cross-Coupling Reactions
Boron Compounds in Chemistry
Publication details
- Journal / source
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 62
- Issue
- 22
- Pages
- 6066–6072
- Publication date
- 1 January 2026
- Language
- EN