Regio- and diastereoselective synthesis of multi-substituted silacyclopentanes by catalytic cyclosilylborylation of styryl(vinyl)silanes
Abstract
Bu-catalyzed regio- and diastereoselective cyclosilylborylation of styryl(vinyl)silanes with silylboronates has been developed for the synthesis of multi-substituted silacyclopentanes. 2-Silyl-5-boryl-1-silacyclopentanes obtained in the present catalysis can be further functionalized by taking advantage of the reactivity of the silyl and boryl groups.
Fields of Study & Subjects
Organoboron and organosilicon chemistry
Catalytic Cross-Coupling Reactions
Synthesis and characterization of novel inorganic/organometallic compounds
Publication details
- Journal / source
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 62
- Issue
- 33
- Pages
- 8461–8465
- Publication date
- 1 January 2026
- Language
- EN