Tetracationic phosphonium-bridged ladder stilbenes: redox states and electronic properties of highly charged P-heteropolycyclic materials

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Authors: Sebastian Senn, Nele Konrad, Jens Müller, Joachim Ballmann, Lutz H. Gade
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Abstract

This work describes the development of an air-stable tetracationic P-heteropolycyclic material in which four phosphorus atoms are incorporated into an extended π-conjugated framework. The system, which may be viewed as a doubly phosphonium-bridged ladder stilbene, was found to display a rich redox chemistry and charge-dependent interaction with DNA.

Fields of Study & Subjects

Synthesis and Properties of Aromatic Compounds Synthesis and characterization of novel inorganic/organometallic compounds DNA and Nucleic Acid Chemistry

Publication details

Journal / source
Chemical Communications
Volume
62
Issue
23
Pages
6391–6395
Publication date
1 January 2026
Language
EN