Mantis-shaped bifunctional tridentate HoMPy-PI-NO ligands capable of cooperatively activating nucleophiles and electrophiles: empowering asymmetric addition reactions

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Authors: Wen-Xiu Geng, Xiongwei Liu, Xiongwei Liu, Wei Xia, N. Wang, Lin Chen, Zhen Yao, Guodong Deng, Xiong‐Li Liu, Xiong‐Li Liu
Cited by: 2
References: 43

Abstract

-oxide ligands, designated "HoMPy-PI-NO ligands". The newly developed ligands could cooperatively activate nucleophiles and electrophiles, exhibiting superior performance in two asymmetric addition reactions to afford functionalized chiral indole derivatives (up to 90% yield, up to 99% ee).

Fields of Study & Subjects

Oxidative Organic Chemistry Reactions Catalytic C–H Functionalization Methods Catalytic Cross-Coupling Reactions

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
27
Pages
7180–7184
Publication date
1 January 2026
Language
EN