Mantis-shaped bifunctional tridentate HoMPy-PI-NO ligands capable of cooperatively activating nucleophiles and electrophiles: empowering asymmetric addition reactions
Abstract
-oxide ligands, designated "HoMPy-PI-NO ligands". The newly developed ligands could cooperatively activate nucleophiles and electrophiles, exhibiting superior performance in two asymmetric addition reactions to afford functionalized chiral indole derivatives (up to 90% yield, up to 99% ee).
Fields of Study & Subjects
Oxidative Organic Chemistry Reactions
Catalytic C–H Functionalization Methods
Catalytic Cross-Coupling Reactions
Publication details
- Journal / source
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 62
- Issue
- 27
- Pages
- 7180–7184
- Publication date
- 1 January 2026
- Language
- EN