Ligand rigidity as a design principle for planar pentacoordinate fluorine

Chemical Communications 2026 Open access

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Authors: Lixia Bai, Yaxuan Cheng, Fernando Martínez-Villarino, Luz Diego, Jin‐Chang Guo, Gabriel Vallejo Merino
DOI: 10.1039/d6cc01294a
Cited by: 1
References: 41

Abstract

as a global minimum. The bonding is predominantly electrostatic with a minor covalent contribution. A detachment energy of 6.29 eV places the cluster in the superhalogen regime.

Fields of Study & Subjects

Inorganic Fluorides and Related Compounds Crystal Structures and Properties Fluorine in Organic Chemistry

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
38
Pages
9749–9753
Publication date
1 January 2026
Language
EN