Mn( ii )-catalyzed switchable synthesis of P(O)–C and P(O)–O bonds from alcohols and diarylphosphine oxides via phospha-Brook rearrangement

Chemical Communications 2026

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Authors: Hirak Jyoti Phukan, Arup Samanta, Kailash Mohar, Avijit Mondal, Rinku Dihingia, Dipankar Srimani
DOI: 10.1039/d6cc01657j
Cited by: 1
References: 34

Abstract

We report a Mn( ii )-catalyzed, biocompatible, and cost-effective method for the selective synthesis of P(O)–O and P(O)–C bonds via dehydrogenative phospha-Brook rearrangement, featuring broad substrate scope.

Fields of Study & Subjects

Asymmetric Hydrogenation and Catalysis Organophosphorus compounds synthesis Catalytic Cross-Coupling Reactions

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
38
Pages
9676–9679
Publication date
1 January 2026
Language
EN