Nickel/copper co-catalysed atroposelective C–Si cross-coupling for the synthesis of axially chiral heterobiaryl silanes

Chemical Communications 2026

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Authors: Lei Su, Shen Gao, Jiawang Liu
DOI: 10.1039/d6cc01681b
Cited by: 1
References: 64

Abstract

)-Si cross-coupling of heterobiaryl triflates with Si-B reagents, providing efficient access to axially chiral silanes. This method offers a broad substrate scope and operational simplicity, establishing a sustainable strategy for constructing valuable chiral silicon-based compounds.

Fields of Study & Subjects

Axial and Atropisomeric Chirality Synthesis Synthesis and Properties of Aromatic Compounds Catalytic Cross-Coupling Reactions

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
44
Pages
11136–11139
Publication date
1 January 2026
Language
EN