Bent ligand-directed assembly and adsorption property modulation of pseudo-tetrahedral polyoxometalate–organic cages
Abstract
Herein, we present a design strategy for novel pseudo-tetrahedral polyoxovanadate-organic cages employing bent bridging ligands and rigid vanadium clusters. The resulting cage structures exhibit tunable iodine capture capabilities, offering a promising route to porous functional materials with specific architectures.
Fields of Study & Subjects
Covalent Organic Framework Applications
Polyoxometalates: Synthesis and Applications
Metal-Organic Frameworks: Synthesis and Applications
Publication details
- Journal / source
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 62
- Issue
- 43
- Pages
- 10858–10862
- Publication date
- 1 January 2026
- Language
- EN