Carbocyclization-oximation of alkenes via boryl radical-mediated halogen atom transfer to access fluorinated 4-(carbaldehyde oxime)quinolinones

Chemical Communications 2026

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Authors: Miao Tian, Qinghao Dong, Ruirui Fu, Yingxue Zhang, Tiantian Chen, Kai Sun
DOI: 10.1039/d6cc02257j
Cited by: 1
References: 51

Abstract

-butyl nitrite (TBN) is reported herein for the cyclizative difunctionalization of alkenes, delivering valuable 4-(carbaldehyde oxime)-fluorinated quinolinones. The protocol operates under mild, metal- and photocatalyst-free conditions, featuring a broad substrate scope, good functional group compatibility, and scalability.

Fields of Study & Subjects

Radical Photochemical Reactions Fluorine in Organic Chemistry Catalytic C–H Functionalization Methods

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
46
Pages
11622–11626
Publication date
1 January 2026
Language
EN