Coordination pyramid inversion, angular cluster core and homochiral single-stranded helix formation in polynuclear Mn( ii ) assemblies supported by a bicompartmental salen-type ligand based on an o -xylylenediamine platform

CrystEngComm 2026

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Authors: Ilya Denisovich Shutilov, Pavel A. Volodin, L. V. Frantsuzova, Губайдуллин Айдар Тимергалиевич, Alexander Ovsyannikov, Svetlana Evgenievna Solovieva, Антипин Игорь Сергеевич
DOI: 10.1039/d6ce00172f
Cited by: 1
References: 88

Abstract

New {MnII2} clusters demonstrate Mn II –N 2 O 2 Cl coordination pyramid inversion and homochiral helix formation, while the {MnII3} counterpart displays the generation of an asymmetric angular cluster core.

Fields of Study & Subjects

Magnetism in coordination complexes Supramolecular Chemistry and Complexes Metal-Organic Frameworks: Synthesis and Applications

Publication details

Journal / source
CrystEngComm
Publisher
Royal Society of Chemistry (RSC)
Volume
28
Issue
20
Pages
3232–3240
Publication date
1 January 2026
Language
EN