Elucidating d–d orbital hybridization in metal-doped MnO 2 for the inhibition of N 2 O formation in NH 3 –SCR

Physical Chemistry Chemical Physics 2026

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Authors: Kai Xie, Ying WANG, Fenghui Li, Haiqiao Wei, Lei ZHOU
DOI: 10.1039/d6cp00271d
Cited by: 1
References: 62

Abstract

Selective d z 2 –p z orbital coupling and d–d hybridization inhibit N 2 O formation in 3d transition metal-doped MnO 2 , showing a volcano relationship, guiding catalyst development and enhancing selectivity via electronic structure control.

Fields of Study & Subjects

Catalytic Processes in Materials Science Ammonia Synthesis and Nitrogen Reduction Advanced Chemical Physics Studies

Publication details

Journal / source
Physical Chemistry Chemical Physics
Publisher
Royal Society of Chemistry (RSC)
Volume
28
Issue
16
Pages
10280–10290
Publication date
1 January 2026
Language
EN