Electron–electrophile coupled dinitrogen reduction in a cerium– meta -tetraphenolate system: a computational study
Abstract
. We establish alkali metal coordination and coupled electron-electrophile transfer as key factors in the design of rare-earth-mediated dinitrogen functionalisation.
Fields of Study & Subjects
Organometallic Complex Synthesis and Catalysis
Ammonia Synthesis and Nitrogen Reduction
Asymmetric Hydrogenation and Catalysis
Publication details
- Journal / source
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 28
- Issue
- 13
- Pages
- 8027–8038
- Publication date
- 1 January 2026
- Language
- EN