[Ru 6 (μ 6 -Sb)(CO) 18 ] 3− : deeply reduced metal carbonyl cluster embedded with naked μ 6 -Sb
Abstract
The redox reaction of K 3 Sb and Ru 3 (CO) 12 in an ethylenediamine solution of 2,2,2-cryptand yielded a deeply reduced Ru–Sb organometallic nanocluster [Ru 6 (μ 6 -Sb)(CO) 18 ] 3− composed of the unusual boat-like Ru 6 cluster unit and unprecedented μ 6 -Sb.
Fields of Study & Subjects
Inorganic Chemistry and Materials
Synthesis and characterization of novel inorganic/organometallic compounds
Organometallic Complex Synthesis and Catalysis
Publication details
- Journal / source
- Dalton Transactions
- Volume
- 55
- Issue
- 10
- Pages
- 4139–4143
- Publication date
- 1 January 2026
- Language
- EN