Half-sandwich η 5 -pyrrolyl rhodium( i ) complexes with alkene coordination: synthesis and reactivity exploration
Abstract
-pyrrolyl ligands are successfully synthesized and fully characterized by X-ray analyses and NMR spectroscopy. The dynamics of pyrrolyl and alkene coordination as well as the combined σ- and π-ligation ability of pyrrolyl are demonstrated in the reactions of these half-sandwich complexes with isocyanide, organic azide and Lewis acid.
Fields of Study & Subjects
Organometallic Complex Synthesis and Catalysis
Synthesis and characterization of novel inorganic/organometallic compounds
Inorganic and Organometallic Chemistry
Publication details
- Journal / source
- Dalton Transactions
- Volume
- 55
- Issue
- 9
- Pages
- 3682–3686
- Publication date
- 1 January 2026
- Language
- EN