Developing Ni 3 N/NiO heterostructure catalysts to enhance the hydrogen evolution reaction in an alkaline medium via a surface-dependent mechanism

Dalton Transactions 2026

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Authors: Fangfang Liu, Shan Ji, Yongwei Li, Zhihao Fang, Vladimir Linkov, Yucheng Dong, Hui Wang
DOI: 10.1039/d6dt00031b
Cited by: 4
References: 57

Abstract

. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) analyses confirm the enhanced capability of this heterostructure in hydrogen adsorption and desorption. Ultraviolet photoelectron spectroscopy (UPS) and X-ray photoelectron spectroscopy (XPS) tests reveal electron rearrangement at the interface, verifying the existence of hydrogen spillover pathways. Additionally, the superhydrophilic-superaerophobic wetting characteristics of the catalyst surface help improve the diffusion rate of reactants and the desorption efficiency of products, thereby further enhancing the overall catalytic stability.

Fields of Study & Subjects

Electrocatalysts for Energy Conversion Ammonia Synthesis and Nitrogen Reduction Hybrid Renewable Energy Systems

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
12
Pages
4832–4840
Publication date
1 January 2026
Language
EN