A di-nuclear μ-oxido rhenium( vi ) complex: from deep purple to catalytic applications

Dalton Transactions 2026 Open access

Read full text
Authors: Tobias A. Doliner, Péter Hartmann, Gernot Oberwinkler, Ferdinand Belaj, Antoine Dupé, A. Daniel Boese, Jörg A. Schachner
DOI: 10.1039/d6dt00039h
Cited by: 2
References: 80

Abstract

the COSMO model. In contrast to isoelectronic µ-oxido bridged Mo(V) complexes, 1 proved to be highly active in catalytic oxyanion reduction, namely perchlorate and nitrate reduction. With a catalyst loading of 5 mol% of 1, a conversion of 90% was observed for perchlorate. These findings highlight that in rhenium chemistry, µ-oxido bridged complexes like 1 still show promising catalyst activities for oxyanion reduction and potentially also other redox transformations.

Fields of Study & Subjects

CO2 Reduction Techniques and Catalysts Metalloenzymes and iron-sulfur proteins Radiopharmaceutical Chemistry and Applications

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
11
Pages
4547–4559
Publication date
1 January 2026
Language
EN