Rigidified cyclic diglycolamides: coordination and extraction of trivalent f-elements

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Authors: Mariia V. Evsiunina, M. V. Kalinin, Paulina Kalle, Danila A. Iakovlev, Stepan N. Kalmykov, Petr Igorevich Matveev, Nataliya E. Borisova
Cited by: 1
References: 80

Abstract

], corresponding to 1 : 1 and 2 : 1 ligand-to-metal stoichiometries, was identified for DGA-based ligands. These findings demonstrate that ligand cyclization significantly affects coordination modes and extraction behavior, highlighting the potential of cyclic DGAs as extractants for nuclear waste management.

Fields of Study & Subjects

Radioactive element chemistry and processing Extraction and Separation Processes Lanthanide and Transition Metal Complexes

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
11
Pages
4638–4656
Publication date
1 January 2026
Language
EN