In or out? Adaptive metal binding by a diphosphine-based Zr metal–organic cage
Abstract
results in formation of Zr-P2N2-Ag, containing a hexasilver core supported by phosphine complexation within the cage interior. This work highlights the adaptive structural behavior of Zr-P2N2 which provides new opportunities for designing responsive MOCs.
Fields of Study & Subjects
Supramolecular Chemistry and Complexes
Organometallic Complex Synthesis and Catalysis
Synthesis and characterization of novel inorganic/organometallic compounds
Publication details
- Journal / source
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 55
- Issue
- 16
- Pages
- 6407–6414
- Publication date
- 1 January 2026
- Language
- EN